Enhanced visible light driven photodegradation of rifampicin and Cr(VI) reduction activity of ultra-thin ZnO nanosheets/CuCo2S4QDs: A mechanistic insights, degradation pathway and toxicity assessment.

In this study, we focused on fabrication of porous ultra-thin ZnO nanosheet (PUNs)/CuCo2S4 quantum dots (CCS QDs) for visible light-driven photodegradation of rifampicin (RIF) and Cr(VI) reduction. The morphology, structural, optical and textural properties of fabricated photocatalyst were critically analyzed with different analytical and spectroscopic techniques. An exceptionally high RIF degradation (99.97%) and maximum hexavalent Cr(VI) reduction (96.17%) under visible light was achieved at 10 wt% CCS QDs loaded ZnO, which is 213% and 517% greater than bare ZnO PUNs. This enhancement attributed to the improved visible light absorption, interfacial synergistic effect, and high surface-rich active sites. Extremely high generation of ●OH attributed to the spin-orbit coupling in ZnO PUNs@CCS QDs and the existence of oxygen vacancies. Besides, the ZnOPUNs@CCS QDs, forming Z-scheme heterojunctions, enhanced the separation of photogenerated charge carriers. We investigated the influencing factors such as pH, inorganic ions, catalyst dosage and drug dosage on the degradation process. More impressively, a stable performance of ZnO PUNs@CCS QDs obtained even after six consecutive degradation (85.9%) and Cr(VI) reduction (67.7%) cycles. Furthermore, the toxicity of intermediates produced during the photodegradation process were assessed using ECOSAR program. This work provides a new strategy for ZnO-based photocatalysis as a promising candidate for the treatment of various contaminants present in water bodies.

Unravelling the enhanced rifampicin photocatalytic degradation over green-synthesized SrO2@SnIn4S8 p-n heterojunction: Pathway, toxicity evaluation and mechanistic insights.

In recent years, the discharge of pharmaceutical drugs into aquatic ecosystems has become a growing concern, posing a significant threat to aquatic life. In response to this environmental challenge, advanced oxidation processes have gained prominence in wastewater treatment due to their efficacy in eliminating pharmaceutical pollutants and their potential for reusability. In this study, we have fabricated SnIn4S8 coupled SrO2 nano-heterojunction (NH) using a greener co-precipitation approach using leaf extract derived from Acaphyla wilkesiana. The resulting NH exhibited exceptional photocatalytic activity against rifampicin (RIF), achieving a remarkable 97.4% degradation under visible light, surpassing the performance of its individual components. The morphological characteristics of the NH were thoroughly analyzed through SEM, TEM, XRD, and XPS techniques, while EIS, DRS, and BET techniques provided valuable insights into its photocatalytic and optical properties. Furthermore, radical scavenging assays and ESR analysis identified hydroxyl radicals (•OH) and superoxide radicals (O2•-) were the species contributing to the visible light-driven photocatalytic degradation. The study also elucidated the potential degradation pathways and intermediates of RIF through GC-MS analysis. Additionally, the toxicity of the produced intermediates was assessed using the ECOSAR model. The findings have significant implications for the treatment of pharmaceutical pollutants and underscore the importance of eco-friendly synthesis methods in addressing environmental challenges.

Interfacial coupling of CuFe2O4 induced hotspots over self-assembled g-C3N4 nanosheets as an efficient photocatalytic bacterial disinfectant.

Most bacterial disinfectants contain high levels of extremely toxic and environmental hazardous chemicals, which pose a significant threat to the ecosystem. Semiconductor photocatalysis exhibits attractive prospects as an emerging greener technology for waste water disinfection. However, the fast recombination of charge carriers limits its practical application. Herein, self-assembled polymeric feather-like g-C3N4 (GCN) nanosheets modified with ferromagnetic CuFe2O4 (CFO) nanospheres were successfully applied as a reusable visible light photocatalytic disinfectant. As expected, the g-C3N4/CuFe2O4 (GCF) nanohybrid displayed superior photocatalytic inactivation efficiency of 0.157log within 120 min towards Escherichia coli DH5α (E. coli) compared with pristine GCN and CFO. The characterization results revealed the synergistic heterostructure interfaces, high surface area, and the transformative self-assembly of GCN to feather-like structure providing a rich active site for improved charge separation efficiency, and wide spectral response, therefore the superior performance of GCF. The radical trapping assay proclaimed that both O2•- and •OH radical played major role in the photocatalytic inactivation among the other reactive oxygen species (ROS). Furthermore, the chemical oxygen demand (COD), protein estimation, and DNA estimation assay results validated the cell damage caused by the photocatalyst. Besides that, GCN showed applicability in real-time wastewater samples with improved efficiency than in the saline solution. The excellent magnetic characteristics facilitated the recycling of the catalyst with insignificant leaching, magnetic induction, and distinguished separation. The results of this work signify the well-designed GCF as a high-performance and reusable photocatalyst for real-world pathogenic bacterial disinfection operations.

Synergistic visible light assisted photocatalytic degradation of p-chlorophenol and rifampicin from aqueous solution using a novel g-C3N4 quantum dots incorporated α-MoO3 nanohybrid - Mechanism, pathway and toxicity studies.

In this work, a simple g-C3N4 quantum dots enriched MoO3 nanohybrid was formulated for the synergistic photocatalytic degradation of an industrially active organic pollutant, p-chlorophenol (PCP) and a widely prescribed antibiotic, rifampicin (RIF). The nanohybrid was synthesised via a facile ultrasonic assisted hydrothermal method and characterized using various characterization analysis. The efficient Z-scheme charge transfer of the nanohybrid resulted in the elimination of 98% PCP and 89% RIF under visible light with a rate constant of 0.012 and 0.006 min-1 respectively. The photocatalysis was attributed to the formation of both hydroxyl (OH•) and superoxide (O2•-) radicals in the resulting nanohybrid. The intermediates formed in the course of reaction were estimated through gas chromatography-mass spectroscopy/mass spectroscopy (GC-MS/MS) analysis and a suitable degradation pathway was constructed. The structural stability and reusability of the nanohybrid was affirmed through X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analysis to outweigh the industrial potential of the catalyst, with 85% PCP and 80% RIF removal efficiency after six cycles of degradation. In addition, the mineralization of the pollutants was confirmed by total organic carbon analysis. Further, the toxicity of the drug and the formed intermediates was determined using ecological structure activity relationships (ECOSAR) software. On the whole, this work provides an excellent insight for the development of environment-friendly materials in a large scale for the degradation of water-based pollutants.

Designing Z-scheme AgIO4 nanorod embedded with Bi2S3 nanoflakes for expeditious visible light photodegradation of congo red and rhodamine B.

The present study describes the enhanced photodegradation of organic pollutant dyes, congo red (CR) and rhodamine B (RhB) dyes under visible light irradiation. AgIO4 nanorods decorated on Bi2S3 nanoflakes in various proportions were synthesized via sono-chemical route wherein the deposition of varying amounts of AgIO4 on Bi2S3 plays a pivotal role in improving the photodegradation ability. The characterization of the as-synthesized nanohybrids was assessed by XRD, UV-vis DRS, PL, EIS, ESR, FT-IR, XPS, HR-TEM, FE-SEM, N2 adsorption and desorption techniques. The effect of initial CR and RhB dye concentration, reaction pH and usage of nanohybrid concentration were investigated where 30%-AgIO4/Bi2S3 exhibited excellent visible light photodegradation of 95.58% for CR and 96.11% for RhB dyes at 140 min and 100 min respectively. The superoxide (•O2-) and hydroxyl radicals (•OH) played predominant role in the photodegradation of CR and RhB which is experimentally confirmed by radical trapping experiments. Also, the photocatalysts exhibited good photo stability and excellent reusability. The TOC analysis confirmed the complete mineralization of CR and RhB dyes by the nanohybrid and the formation of possible intermediate and degradation pathway was delineated based on GC/MS analysis. The outstanding photodegradation performance were ascribed to the Z-scheme charge transfer path, which effectively promotes the separation and transfer of e-/h+ pairs, resulting in a strong redox activity of the accumulated charge to decompose organic dyes during the degradation reaction. The study suggested that the nanohybrid can be utilized for the removal of organic pollutants from the contaminated water bodies.

Recent developments in architecturing the g-C3N4 based nanostructured photocatalysts: Synthesis, modifications and applications in water treatment.

Water pollution is becoming an inevitable problem in today's world. Tons and tons of wastewater with hazardous pollutants are getting discharged into the clean water bodies every day. In this regard, photocatalytic environmental remediation using nanotechnology such as the use of organic, metal and non-metal based semiconductor photocatalysts for photodegradation of pollutants has gained enormous attention in the past few decades. This review is focused particularly on graphitic carbon nitride (g-C3N4) which is a cheap, metal-free, polymeric photoactive compound and it is used as a potential photocatalyst in wastewater treatment. Though, pristine g-C3N4 is a good photocatalyst, it has certain drawbacks such as poor visible light absorption capacity, quicker recombination of photoelectrons and holes, delayed mass and charge transfer, etc. As a result, the pristine g-C3N4 catalyst is modified into novel 0D, 1D, 2D and 3D morphologies such as nano-quantum dots, nanorods, nanotubes, nanowires, nanosheets, nanoflakes, nanospheres, nanoshells, etc. It was also tailored into novel composites along with various compounds through doping, metal deposition, heterojunction formation, etc., to enhance the photocatalytic property of pure g-C3N4. The modified catalysts showed promising photocatalytic performance such as degradation of majority of pollutants in the environment. It also showed excellent results in the removal or reduction of heavy metals. This review provides a detailed record of g-C3N4 and its diverse photocatalytic applications in the past years and it provides knowledge for the development of such similar novel compounds in the future.

Recent advances in degradation of organic pollutant in aqueous solutions using bismuth based photocatalysts: A review.

Today, a major concern associated with the environment is the water pollution occurred due to the introduction of variety of persistent organic pollutants and residual dyes from different sources (e.g., dye and dye intermediates industries, paper and pulp industries, textile industries, tannery and craft bleaching industries, pharmaceutical industries, etc.) into our natural water resources. Recently, advanced oxidation processes (AOPs) by photocatalyst have garnered great attention as a new frontier promising eco-friendly and sustainable wastewater treatment technology. Utilization of the photocatalytic technology efficiently is significant for cleaner environment. Bismuth based photocatalyst have aroused widespread attention as a visible light responsive photocatalyst for waste water treatment due to their non-toxicity, low cost, modifiable morphology, and outstanding optical and chemical properties. In this review, we have dealt with the research progress on bismuth-based photocatalysts for waste water treatment. However, it seems to give limitation over pristine photocatalysts such as slow migration of charge carriers, charge carrier recombination, low visible light absorption, etc., Various bismuth based photocatalyst and its modifications via doping, heterojunction, Z-scheme etc., are discussed in detail. Further, the strategies adopted to improve the photocatalytic activity of bismuth based photocatalyst to improve the waste water treatment (mostly drugs and dyes) are critically reviewed. Also, we have discussed the bacterial inactivation by bismuth based photocatalyst. Finally, the challenges and future aspects against bismuth based photocatalyst are explored for further research.

Ag0 decorated Cr2S3 NPs embedded on PVP matrix: A colorimetric probe for selective and rapid detection of sulphide ions from environmental samples.

Globally, the environmental pollution is one of the major issues causing toxicity towards human and aquatic life. We have developed a facile and innovative sensing approach for detection of sulphide ions (S2-) present in the aqueous media using Ag0 decorated Cr2S3 NPs embedded on PVP matrix (Ag/Cr2S3-PVP). Based on the SPR phenomena, the detection of S2- ions was established. The nanohybrid was characterized using various techniques such as UV-vis spectrophotometer, High-Resolution Transmission Electron Microscopy (HR-TEM), Thermal Gravimetric Analysis (TGA), X-ray diffraction analysis(XRD), Energy-dispersive X-ray spectroscopy (EDS), Fourier-transform infrared spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The yellowish colour of Ag/Cr2S3-PVP nanohybrid turned to brown colour in presence of S2- ions. The selectivity and sensitivity of the prepared probe was studied against the other interfering metal ions. In addition, the effect of different concentration of S2- ions in the nanohybrid solution was investigated and the Limit of detection (LOD) was found to be 6.6 nM. The good linearity was found over the range of 10 nM to 100 µM with R2 value of 0.981. The paper strip based probe was developed for rapid onsite monitoring of S2- ions. The proposed method is found to be cost-effective, rapid, and simple. We have validated the practical applicability of the prepared probe for determining the concentration of S2- ions in real water samples.

Highly selective and sensitive tool for the detection of Hg(II) using 3-(Trimethoxysilyl) propyl methacrylate functionalized Ag-Ce nanocomposite from real water sample.

Mercury and its derivates cause distinct toxicity and it is detrimental to the ecosystem where the excessive concentration contributes towards the environmental pollutants. The current study reported a colorimetric method for the detection of Hg(II) ion with high specificity and selectivity using Ag-Ce nanocomposite (NC) functionalized by 3-(Trimethoxysilyl) propyl methacrylate. The synthesized Ag-Ce NC was characterized by using double beam UV-visible spectrophotometer, zeta sizer, EDS, TEM, FT-IR, XRD and particle size analyzer. The synthesized particle possessed an average particle size of 27 ±â€¯1 nm and zeta potential of -39.32 ±â€¯3 mV. The brownish yellow colored Ag-Ce NC changed to colorless in presence of Hg(II) where the colorimetric detection was extremely specific and superior towards Hg(II) ion on comparing the tests with other metal ions. An excellent linear correlation was observed between absorbance (395 nm) and Hg(II) concentrations (1 nM-10 µM) (R2 = 0.988) with LOD of 0.03 nM. A cotton swab based probe was prepared for selective, elegant and low cost colorimetric method to detect Hg(II). The parametric study was performed for optimizing the suitable condition. The colorimetric probe developed by this study for Hg(II) detection using Ag-Ce NC shows excellent practical applicability.